Xenial (Ubuntu 16) is only in standard support until 2021. After that, there is only extended security-only support. Which means your server is 'on life support' so to speak.
So extended-security support is meant to keep a server alive, not to update it with new features and new software.
Extended security support (ESM, or maybe called Ubuntu Pro these days) is a sort of 'paid for' support option. You can get it free for a limited number of installations, though. But it clearly 'is not for everyone'.
Ondrej (the maintainer of that PPA repository with PHP versions for Ubuntu) does not want to support versions that are outside standard support, which sounds perfectly fine by the way.
So you can't download any Xenial packages anymore, because he removed them. Maybe someone still has a Xenial server running with his php8.0 packages on there, but those packages will not be updated, so you are just as safe as to compile your own version from source if you need to run it.
These are the negatives about opting in for extended support programs. Yes, you receive security updates for something that would otherwise be out of life. But you should not think that your server is then 'just fine the way it is' with ESM. All around the Ubuntu community and other commercial packages, you will see Xenial support being dropped, even if you still have ESM for years to come.
So use ESM only as a means to postpone an upgrade if you really have to, but do not let it stick around it for years.