The contents of the EFI partition should be relatively stable, so manually cloning changes to other copies on other disks after updates should be fine. And even if changes are not cloned, old copies might be OK as long as they are not too many revisions behind.
Will the system boot off of an alternate EFI? That's a harder question. Most modern bios versions do support multiple boot devices and may try them all in sequence until one works. So then you just have to make sure they are all there and in the correct order. You may need to manually run the linux command to update the EFI bootloader list and order.
However, it might be better to not have it autoboot on failure. If the primary EFI disk fails, you may want to manually boot and attempt repairs anyway. But having the backup EFI even if it isn't in the boot order should make recovery a lot easier.
An alternate viewpoint -- if a disk in a raid system is going to fail, it is likely to fail when the system is up. If you detect this condition before the next boot, you can easily activate one of your backup EFI copies (and maybe even make it primary) until the failed disk is replaced.